EDIT Earliest use Braces { } are found in the 1593 edition of Francois Vieta's Zetetica.

Source: A History of Mathematical Notations, Cajori, vol. 1, page 391
 
EDIT Synonyms
North American English: braces
French: Akkolade (hug)
 
EDIT Use Brackets generally serve to enclose textual material and to differentiate between various additions to a sentence (inserted sentences, letters, parts of words).
Curly brackets are hardly ever used in continuous text, they are used additionally when parenthesis and square brackets are already in use. The sequence is: square brackets are used for insertions into parenthesis, curly brackets are inserted into square brackets ([{}]).
 
EDIT Mathematics In mathematical formulas brackets have a very strict order. The curly brackets are the outermost ones after the parethesis and the square brackets.

Also, in mathematics a set can be defined by listing its members between curly Brackets :

A = {3, 1, 4, 2,5}
B = {cyan, magenta, yellow, black}

(the other option is do describe it in words, like: »A is the set whose members are the first five positive whole numbers« or »B is the set whose members are the four colours used for printing).
 
EDIT Programming In computer programming, curly brackets sometimes denote the beginning and ending of a sequence of statements.
 
EDIT Music The curly brackets connect two or more lines of music that are played simultaneously.
 
ADD NEWSIMILAR CHARACTERS
01 CODE POINT VALUE: : : : : 007B
02 NAME (UNICODE NAME) : : : LEFT CURLY BRACKET
03 GENERAL CATEGORY: : : : : Punctuation, Open
04 COMBINING CLASS : : : : : Spacing, split, enclosing, reordrant, and Tibetan subjoined
05 BIDIRECTIONAL CATEGORY: : Other Neutrals
06 DECOMPOSITION MAPPING : : -
07 DECIMAL DIGIT VALUE : : : -
08 DIGIT VALUE : : : : : : : -
09 NUMERIC VALUE : : : : : : -
10 MIRRORED: : : : : : : : : Yes
11 UNICODE 1.0 NAME: : : : : LEFT CURLY BRACKET
12 ISO 10646 COMMENT FIELD : -
 
13  UPPERCASE MAPPING : : : : -
14 LOWERCASE MAPPING : : : : -
15 TITLECASE MAPPING : : : : -
16 DECIMAL VALUE : : : : : : 123
17 UTF-8 HEX VALUE : : : : : 0x7B
18 UTF-16 HEX VALUE: : : : : 0x007B
19 UTF-32 HEX VALUE: : : : : 0x0000007B
20 XHTML : : : : : : : : : : &#123
21 BLOCK : : : : : : : : : : Basic Latin
22 PLANE : : : : : : : : : : Basic Multilingual Plane (BMP)
23 STROKE NUMBER : : : : : : -
24 RADICAL : : : : : : : : : -
 < CHARACTER >  BLOCK PROPERTIES
U+007B LEFT CURLY BRACKET
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